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Radical Hydroalkylation and Hydroacylation of Alkenes by the Use of Benzothiazoline under Thermal Conditions.
The Journal of Organic Chemistry ( IF 3.6 ) Pub Date : 2020-09-08 , DOI: 10.1021/acs.joc.0c01872
Tatsuhiro Uchikura 1 , Mitsuhiro Toda 1 , Toshiki Mouri 1 , Tatsuya Fujii 1 , Kaworuko Moriyama 1 , Ignacio Ibáñez 1 , Takahiko Akiyama 1
Affiliation  

The hydroalkylation and hydroacylation of electron-deficient alkenes proceeded smoothly by using benzothiazoline derivatives as radical-transfer reagents under thermal conditions without light irradiation or any additive. Both benzyl and benzoyl moieties were transferred efficiently.

中文翻译:

在热条件下使用苯并噻唑啉进行烯烃的自由基加氢烷基化和加氢酰化。

通过使用苯并噻唑啉衍生物作为自由基转移试剂,在没有光照或没有任何添加剂的热条件下,将电子不足的烯烃的加氢烷基化和加氢酰化反应顺利进行。苄基和苯甲酰基部分均被有效转移。
更新日期:2020-10-02
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