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Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation.
Inorganic Chemistry ( IF 4.6 ) Pub Date : 2020-09-09 , DOI: 10.1021/acs.inorgchem.0c00638 Vitor C Weiss 1, 2 , Giliandro Farias 1 , André L Amorim 1 , Fernando R Xavier 3 , Tiago P Camargo 4 , Mayana B Bregalda 4 , Matti Haukka 5 , Ebbe Nordlander 6 , Bernardo de Souza 1 , Rosely A Peralta 1
Inorganic Chemistry ( IF 4.6 ) Pub Date : 2020-09-09 , DOI: 10.1021/acs.inorgchem.0c00638 Vitor C Weiss 1, 2 , Giliandro Farias 1 , André L Amorim 1 , Fernando R Xavier 3 , Tiago P Camargo 4 , Mayana B Bregalda 4 , Matti Haukka 5 , Ebbe Nordlander 6 , Bernardo de Souza 1 , Rosely A Peralta 1
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The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.
中文翻译：
发光PhotoCORM：启用/禁用蓝光照射下的CO输送。
合成了新型发光羰基化合物[Mn（Oxa-H）（CO）3 Br]（1）和[Mn（Oxa-NMe 2）（CO）3 Br]（2）。配合物1和2显示出在蓝光（λ453）下的CO释放。光谱技术和TD-DFT和SOC-TD-DFT计算表明，除羰基配体外，1和2还释放了Oxa-H和Oxa-NMe 2大分子，从而增加了光诱导过程中的发光。
更新日期：2020-09-21
中文翻译：
发光PhotoCORM：启用/禁用蓝光照射下的CO输送。
合成了新型发光羰基化合物[Mn（Oxa-H）（CO）3 Br]（1）和[Mn（Oxa-NMe 2）（CO）3 Br]（2）。配合物1和2显示出在蓝光（λ453）下的CO释放。光谱技术和TD-DFT和SOC-TD-DFT计算表明，除羰基配体外，1和2还释放了Oxa-H和Oxa-NMe 2大分子，从而增加了光诱导过程中的发光。
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