Hydrogen generation via artificial photosynthesis paves a promising way to remit the ever-increasing energy crisis and deteriorative environmental issues. Among all the materials utilized for solar hydrogen production, perovskite has emerged as a rising star due to its superior optoelectronic properties. This manuscript aims to provide a comprehensive review summarizing the recent inspiring advancements on perovskite-based solar hydrogen production systems, including the particulate photocatalysis, photoelectrochemical cells, and photovoltaic-electrocatalytic cells. We start with a brief introduction of the advantages of perovskites for solar hydrogen production and the basic principles of the three most prominent solar hydrogen production systems. The representative progresses in this field are then detailed with a special emphasis on the strategies to improve the efficiency and the stability of the systems. Finally, challenges and opportunities for the further development of the PVK-based solar hydrogen production systems are presented with perspective given on outlook, performance, cost and stability.

通过人工光合作用产生氢为缓解日益严重的能源危机和环境恶化问题铺平了道路。在用于太阳能制氢的所有材料中，钙钛矿因其卓越的光电性能而成为后起之秀。该手稿旨在提供全面的综述，概述基于钙钛矿的太阳能制氢系统（包括颗粒光催化，光电化学电池和光伏电催化电池）的最新启发。我们首先简要介绍钙钛矿在太阳能氢生产中的优势以及三种最著名的太阳能氢生产系统的基本原理。然后详细介绍了该领域的代表性进展，并特别着重于提高系统效率和稳定性的策略。最后，从前景，性能，成本和稳定性的角度介绍了基于PVK的太阳能制氢系统进一步发展所面临的挑战和机遇。