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C2 symmetric borneol-porphyrin hybrids: Synthesis, characterization, electronic structure and their anti-cancer behaviors
Dyes and Pigments ( IF 4.5 ) Pub Date : 2020-09-08 , DOI: 10.1016/j.dyepig.2020.108837
Bo Fu , Zhen Zhang , Xiaoxiao Yu , Xinyi Dong , Xianying Fang , Weihua Zhu , Xu Liang , Haijun Xu

A series of five C2 Symmetric A2B2 type borneol-porphyrin hybrids have been synthesized and characterized. Moreover, a detailed analysis of their optical and redox properties was carried out by comparing the results obtained via optical spectroscopy and electrochemistry. The current results demonstrated that the meso borneol-substitutions excitation coupled strongly with porphyrin core that leads to significant CD signals in the Soret band region, and molecular anti-cancer behaviors were also investigated.



中文翻译:

C 2对称冰片-卟啉杂化物:合成,表征,电子结构及其抗癌行为

已经合成并表征了一系列五个C 2对称的A 2 B 2型冰片-卟啉杂化物。此外,通过比较通过光谱学和电化学获得的结果,对它们的光学和氧化还原性质进行了详细的分析。目前的结果表明,内消旋的冰片取代激发与卟啉核心强烈耦合,导致在Soret带区域产生明显的CD信号,并且还研究了分子抗癌行为。

更新日期:2020-09-14
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