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Electrochemical aspects of sol-gel synthesized MgCoO2 for aqueous supercapacitor and alkaline HER electrocatalyst applications
Current Applied Physics ( IF 2.4 ) Pub Date : 2020-12-01 , DOI: 10.1016/j.cap.2020.08.021
S. Maitra , P.K. Chakraborty , R. Mitra , T.K. Nath

Abstract We report here the cost-effective synthesis of Magnesium Cobalt Oxide (MgCoO2) sample by the sol-gel synthesis route labeled as MCO - 3. In presence of aqueous 1 M Lithium Sulphate (Li2SO4) electrolyte, we obtained a capacitance of 56 F/g, an energy density of 38 Wh/kg and a capacitance retention of 92.53 % (at 5 A/g) after undergoing 1000 charge-discharge cycles. For the aqueous 1 M Sodium Perchlorate (NaClO4) electrolyte system, we found the capacitance, energy density and capacitance retention of 47 F/g, 31 Wh/kg and 91.41% (at 3.5 A/g for 1000 charge-discharge cycles), respectively. These results establish MgCoO2 as suitable electrode material in aqueous lithium-ion and sodium-ion supercapacitor devices. Further, MCO - 3 in the presence of aqueous 1 M Potassium Hydroxide (KOH) electrolyte showed an overpotential of 400 mV and a Tafel slope of 174 mV/dec, making it a suitable candidate for alkaline Hydrogen Evolution Reaction (HER) electrocatalyst.

中文翻译:

用于水性超级电容器和碱性 HER 电催化剂应用的溶胶-凝胶合成 MgCoO2 的电化学方面

摘要 我们在此报告了通过标记为 MCO-3 的溶胶-凝胶合成路线经济高效地合成氧化镁 (MgCoO2) 样品。在 1 M 硫酸锂 (Li2SO4) 电解质存在下,我们获得了 56 F 的电容/g,在经历 1000 次充放电循环后,能量密度为 38 Wh/kg,电容保持率为 92.53%(5 A/g)。对于 1 M 高氯酸钠 (NaClO4) 水溶液电解质系统,我们发现电容、能量密度和电容保持率为 47 F/g、31 Wh/kg 和 91.41%(在 3.5 A/g 下进行 1000 次充放电循环),分别。这些结果确立了 MgCoO2 作为水性锂离子和钠离子超级电容器装置中合适的电极材料。更多,
更新日期:2020-12-01
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