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Ledge-directed epitaxy of continuously self-aligned single-crystalline nanoribbons of transition metal dichalcogenides.
Nature Materials ( IF 41.2 ) Pub Date : 2020-09-07 , DOI: 10.1038/s41563-020-0795-4
Areej Aljarb , Jui-Han Fu , Chih-Chan Hsu , Chih-Piao Chuu , Yi Wan , Mariam Hakami , Dipti R. Naphade , Emre Yengel , Chien-Ju Lee , Steven Brems , Tse-An Chen , Ming-Yang Li , Sang-Hoon Bae , Wei-Ting Hsu , Zhen Cao , Rehab Albaridy , Sergei Lopatin , Wen-Hao Chang , Thomas D. Anthopoulos , Jeehwan Kim , Lain-Jong Li , Vincent Tung

Two-dimensional transition metal dichalcogenide nanoribbons are touted as the future extreme device downscaling for advanced logic and memory devices but remain a formidable synthetic challenge. Here, we demonstrate a ledge-directed epitaxy (LDE) of dense arrays of continuous, self-aligned, monolayer and single-crystalline MoS2 nanoribbons on β-gallium (iii) oxide (β-Ga2O3) (100) substrates. LDE MoS2 nanoribbons have spatial uniformity over a long range and transport characteristics on par with those seen in exfoliated benchmarks. Prototype MoS2-nanoribbon-based field-effect transistors exhibit high on/off ratios of 108 and an averaged room temperature electron mobility of 65 cm2 V−1 s−1. The MoS2 nanoribbons can be readily transferred to arbitrary substrates while the underlying β-Ga2O3 can be reused after mechanical exfoliation. We further demonstrate LDE as a versatile epitaxy platform for the growth of p-type WSe2 nanoribbons and lateral heterostructures made of p-WSe2 and n-MoS2 nanoribbons for futuristic electronics applications.



中文翻译:

过渡金属二卤化物的连续自对准单晶纳米带的壁架定向外延。

二维过渡金属二硫化碳纳米带被吹捧为高级逻辑和存储设备的未来极端设备缩减规模,但仍然是一个巨大的合成挑战。这里,我们证明连续的,自对准的,单层膜和单晶的MoS的密集阵列的一个凸缘定向外延(LDE)2个纳米带对β-镓(III)氧化物(的β-Ga 2 ö 3)(100)衬底。LDE MoS 2纳米带具有长距离的空间均匀性,并且具有与剥落基准中看到的相当的传输特性。基于MoS 2纳米核的原型场效应晶体管的开/关比很高,为10 8平均室温电子迁移率为65 cm 2  V -1  s -1。所述MOS 2纳米带可以很容易地转移到任意的基材,而下层的β-Ga 2 ö 3可以机械剥离后可重复使用。我们进一步证明LDE是通用的外延平台,用于生长p型WSe 2纳米带和由p-WSe 2和n-MoS 2纳米带制成的横向异质结构,用于未来电子应用。

更新日期:2020-09-08
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