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High-temperature corrosion of spark plasma sintered Gd2SiO5 with volcanic ash for environmental barrier coatings
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-09-06 , DOI: 10.1016/j.jeurceramsoc.2020.09.001
Seung-Hyeon Kim , Byung-Nam Kim , Nobuo Nagashima , Yoshitaka Matsushita , Byung-Koog Jang

Hot corrosion behavior was evaluated by gadolinium monosilicate (Gd2SiO5) with volcanic ash for environmental barrier coatings (EBCs). Sintered Gd2SiO5 was prepared by the spark plasma sintering (SPS) method at 1400 °C for 20 min, and high-temperature corrosion resistance against of volcanic ash was evaluated at 1400 °C for 2 h, 12 h, and 48 h. The surface region of sintered Gd2SiO5 was partially dissolved in molten volcanic ash, creating a chemically reacted area. The formation of the elongated morphology of Ca2Gd8(SiO4)6O2 grains observed in the reaction area is thicker with increasing heat-treatment time as the volcanic ash dissolves. In addition, high-temperature X-ray diffraction was carried out to identify the dynamics of phase evaluation in the volcanic ash and Gd2SiO5. According to the results, corrosion occurs due to reaction of the Gd2SiO5 phase and the Ca component of volcanic ash at 1300 °C, and the Ca2Gd8(SiO4)6O2 phase is generated.



中文翻译:

火山灰对火花等离子体烧结Gd 2 SiO 5的高温腐蚀,用于环境屏障涂料

通过具有火山灰的单硅酸g(Gd 2 SiO 5)评估了热腐蚀行为,用于环境屏障涂料(EBC)。通过火花等离子体烧结(SPS)方法在1400°C下20 min制备烧结的Gd 2 SiO 5,并在1400°C下评估2 h,12 h和48 h的耐火山灰的高温腐蚀性能。烧结的Gd 2 SiO 5的表面部分溶解在熔融的火山灰中,形成化学反应区域。Ca 2 Gd 8(SiO 46 O 2的伸长形态的形成随着火山灰的溶解,随着热处理时间的增加,在反应区域观察到的晶粒变厚。另外,进行了高温X射线衍射,以鉴定火山灰和Gd 2 SiO 5中的相评价动力学。根据该结果,由于Gd 2 SiO 5相与火山灰的Ca成分在1300℃下的反应而发生腐蚀,生成Ca 2 Gd 8(SiO 46 O 2相。

更新日期:2020-09-06
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