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Effect of selected ammonia escape inhibitors on carbon dioxide capture and utilization via calcium carbonate precipitation
Journal of CO2 Utilization ( IF 7.7 ) Pub Date : 2020-09-03 , DOI: 10.1016/j.jcou.2020.101298
Natalia Czaplicka , Donata Konopacka-Łyskawa , Barbara Kościelska , Marcin Łapiński

Carbon dioxide was used to precipitate CaCO3 with CaCl2 solution in the presence of NH3 as a CO2 absorption promoter. Compounds that were previously indicated as inhibitors of ammonia escape during CO2 absorption were also added to the reaction mixture. Inorganic salts, i.e. ZnCl2, CuCl2, CoCl2, and organic substances, i.e. glycerol, ethylene glycol and triethanolamine were tested inhibitors in this work. A model post-distillation liquid from the Solvay process was used as the reaction mixture, while the gas stream fed into the system had a composition corresponding to the exhausted gases produced by the fossil fuels combustion. The purpose of this research was to investigate the efficiency of CO2 sequestration and the consumption of calcium ions during precipitation in the carbonation processes and determine the characteristics of produced CaCO3 particles. Of the tested additives, glycerol turned out to be the most effective, because its presence resulted in increased calcium ion consumption and CO2 sequestration compared to the control process. 90.5 % CO2 sequestration and 88.1 % Ca2+ consumption were obtained. The CaCO3 particles obtained in the presence of all tested organic inhibitors were in the form of vaterite and were characterized by a significantly larger specific surface area and larger pore volume.



中文翻译:

选定的氨逃逸抑制剂通过碳酸钙沉淀对二氧化碳捕获和利用的影响

在NH 3作为CO 2吸收促进剂的情况下,使用二氧化碳用CaCl 2溶液沉淀CaCO 3。还向反应混合物中添加了以前指示为吸收CO 2期间氨逸出的抑制剂的化合物。无机盐,即ZnCl 2,CuCl 2,CoCl 2,并且有机物质,即甘油,乙二醇和三乙醇胺,在这项工作中被测试为抑制剂。将来自索尔维工艺的典型蒸馏后液体用作反应混合物,同时送入系统的气流的成分与化石燃料燃烧产生的废气相对应。这项研究的目的是研究碳酸化过程中沉淀过程中CO 2的螯合效率和钙离子的消耗,并确定产生的CaCO 3颗粒的特性。在测试的添加剂中,甘油被证明是最有效的,因为它的存在会导致钙离子消耗量增加和CO 2增加。隔离相比控制过程。获得了90.5%的CO 2固存和88.1%的Ca 2+消耗量。在所有测试的有机抑制剂的存在下获得的CaCO 3颗粒呈球ate石形式,其特征在于明显更大的比表面积和更大的孔体积。

更新日期:2020-09-05
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