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Hydrocracking diversity in n -dodecane isomerization on Pt/ZSM-22 and Pt/ZSM-23 catalysts and their catalytic performance for hydrodewaxing of lube base oil
Petroleum Science ( IF 5.6 ) Pub Date : 2020-09-04 , DOI: 10.1007/s12182-020-00500-7
Shan-Bin Gao , Zhen Zhao , Xue-Feng Lu , Ke-Bin Chi , Ai-Jun Duan , Yan-Feng Liu , Xiang-Bin Meng , Ming-Wei Tan , Hong-Yue Yu , Yu-Ge Shen , Meng-Chen Li

Nobel metallic Pt/ZSM-22 and Pt/ZSM-23 catalysts were prepared for hydroisomerization of normal dodecane and hydrodewaxing of heavy waxy lube base oil. The hydroisomerization performance of n-dodecane indicated that the Pt/ZSM-23 catalyst preferred to crack the C–C bond near the middle of n-dodecane chain, while the Pt/ZSM-22 catalyst was favorable for breaking the carbon chain near the end of n-dodecane. As a result, more than 2% of light products (gas plus naphtha) and 3% more of heavy lube base oil with low-pour point and high viscosity index were produced on Pt/ZSM-22 than those on Pt/ZSM-23 while using the heavy waxy vacuum distillate oil as feedstock.



中文翻译:

Pt / ZSM-22和Pt / ZSM-23催化剂在正十二烷异构化中的加氢裂化多样性及其对润滑油基础油加氢脱蜡的催化性能

制备了诺贝尔金属Pt / ZSM-22和Pt / ZSM-23催化剂,用于正十二烷的加氢异构化和重蜡质润滑油基础油的加氢脱蜡。正十二烷的加氢异构化性能表明,Pt / ZSM-23催化剂更喜欢使十二烷链中部附近的C–C键断裂,而Pt / ZSM-22催化剂则有利于破坏碳纳米管附近的碳链。十二烷的末端。结果,与Pt / ZSM-23相比,在Pt / ZSM-22上生产了2%以上的轻质产品(天然气加石脑油)和3%以上的具有低倾点和高粘度指数的重油基础油。同时使用重蜡质真空蒸馏油作为原料。

更新日期:2020-09-05
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