Fullerenes, Nanotubes and Carbon Nanostructures ( IF 2.3 ) Pub Date : 2020-09-03 E. F. Sheka, Ye. A. Golubev, N. A. Popova
Two-mode valence electron configuration of carbon atoms lays the foundation of the unique two-mode amorphous state of the carbon solid. From the fundamentals of solid-state physics, sp3 and sp2 amorphous carbons are two different species characterized by conceptually different short-range orders, namely, groups of tetrahedrally bonded sp3 configured atoms and nanoscale size-restricted sp2 graphene domains framed with heteroatom necklaces. Molecular character of sp2 amorphics is provided with chemical reactions accompanying the solids amorphization in due course of the enforced fragmentation.
中文翻译:
sp2固体碳的非晶态
碳原子的二态价电子构型为碳固体独特的二态非晶态奠定了基础。从固态物理学的基本原理来看,sp 3 和sp 2 非晶碳是两个不同的物种,其特征在于概念上的短程有序,即四面体键合的sp 3 构型原子组和纳米级尺寸受限的sp 2 石墨烯结构域杂原子项链。在强制性断裂的适当过程中,伴随固体非晶化的化学反应提供了sp 2 非晶态的分子特征。