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Co2(CO)8-Catalyzed Reactions of Acetals or Lactones with Hydrosilanes and Carbon Monoxide. A New Access to the Preparation of 1,2-Diol Derivatives through Siloxymethylation
Bulletin of the Chemical Society of Japan ( IF 4 ) Pub Date : 2021-01-15 , DOI: 10.1246/bcsj.20200240
Naoto Chatani 1 , Satoru Fujii 1 , Yoichi Kido 1 , Yasuhide Nakayama 1 , Yasuteru Kajikawa 1 , Hideo Tokuhisa 1 , Yoshiya Fukumoto 1 , Shinji Murai 1
Affiliation  

The Co2(CO)8-catalyzed reaction of acetals with hydrosilanes and CO under mild reaction conditions (an ambient temperature under an ambient CO pressure), leading to the production of vicinal diols ...

中文翻译:

Co2(CO)8 催化缩醛或内酯与氢硅烷和一氧化碳的反应。甲硅烷氧基甲基化制备 1,2-二醇衍生物的新途径

Co2(CO)8 催化缩醛与氢硅烷和 CO 在温和反应条件(环境温度和环境 CO 压力)下反应,生成邻二醇...
更新日期:2021-01-15
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