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CO2 Capture with Silylated Ethanolamines and Piperazines.
ChemistryOpen ( IF 2.3 ) Pub Date : 2020-09-02 , DOI: 10.1002/open.202000212
Marcus Herbig 1 , Lia Gevorgyan 1 , Moritz Pflug 1 , Jörg Wagler 1 , Sandra Schwarzer 1 , Edwin Kroke 1
Affiliation  

Invited for this month's cover is the group of Marcus Herbig from the TU Bergakademie in Freiberg. The cover picture shows the reaction of CO2 with a silyl derivative of the biogenic amine ethanolamine. The role of CO2 as a contributor to climate change makes “carbon capture” a desirable goal. However, in addition to simply capture CO2, aminosilanes form silylcarbamates, which represent starting materials for a variety of crucial chemicals. Thus, the entrapped CO2 represents a useful C1 building block. The ESF‐funded Junior Research Group CO2‐Sil at the TU Bergakademie Freiberg (represented by their Logo and location) pursues that kind of goals. CO2‐Sil studies these key reactions of CO2 insertion in depth by syntheses, quantum chemical calculations and calorimetric experiments. CO2 brought to the ground by our method shall be feedstock for various branches in chemistry. Read the full text of their Full Paper at 10.1002/open.201900269.

中文翻译:

使用硅烷化乙醇胺和哌嗪捕获 CO2。

本月的封面邀请是来自弗赖贝格的 TU Bergakademie 的 Marcus Herbig 小组。封面图片显示了 CO 2与生物胺乙醇胺的甲硅烷基衍生物的反应。CO 2作为气候变化贡献者的作用使“碳捕获”成为一个理想的目标。然而,除了简单地捕获 CO 2之外,氨基硅烷还形成甲硅烷基氨基甲酸酯,它代表了各种关键化学品的起始材料。因此,截留的CO 2代表有用的C 1结构单元。由 ESF 资助的 TU Bergakademie Freiberg 初级研究小组 CO 2 -Sil(以他们的徽标和位置为代表)追求这种目标。二氧化碳2-Sil通过合成、量子化学计算和量热实验深入研究了CO 2插入的这些关键反应。通过我们的方法带到地面的CO 2将成为化学各个分支的原料。在 10.1002/open.201900269 阅读他们的全文。
更新日期:2020-09-02
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