Abstract We investigate whether the thin-film carbon Raman spectral form is determined by the location of the corresponding sample within the framework of a ternary phase characterization of thin-film carbon. We do this through a critical examination of a collection of experimentally acquired Raman spectra corresponding to an ensemble of thin-film carbon samples, whose sp2 and sp3 bonding contents and hydrogen content are known. Both qualitative and quantitative analyzes are pursued. For our qualitative analysis, we compare the gross features of the various Raman spectra considered in this analysis. For our quantitative analysis, the Raman spectral intensity at key spectral reference points are evaluated. Within the scope of its limitations, our analysis does confirm that there is indeed a relationship between the form of the Raman spectrum and the location of the corresponding sample within the thin-film carbon genome, as defined by the ternary phase diagram.

中文翻译：

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拉曼光谱形式与相应样品在整个薄膜碳基因组中的位置之间的关系

摘要 我们研究了薄膜碳拉曼光谱形式是否由相应样品在薄膜碳三元相表征框架内的位置决定。我们通过对一组实验获得的拉曼光谱进行严格检查来做到这一点，这些拉曼光谱对应于一组薄膜碳样品，其 sp2 和 sp3 键含量和氢含量是已知的。进行定性和定量分析。对于我们的定性分析，我们比较了本分析中考虑的各种拉曼光谱的总体特征。对于我们的定量分析，评估了关键光谱参考点的拉曼光谱强度。在其限制范围内，