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Development of novel temperature-stable Al2O3–TiO2-based dielectric ceramics featuring superior thermal conductivity for LTCC applications
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-09-02 , DOI: 10.1016/j.jeurceramsoc.2020.08.072
Koichi Shigeno , Moyuan Li , Hirotaka Fujimori

A new composition was developed using sintering to improve the dielectric properties of low-temperature co-fired alumina (LTCA) containing CuO–TiO2–Nb2O5–Ag2O. By substituting some alumina with rutile TiO2, the second-phase compound could be changed from AgNbO3 to the rutile phase. Further, low-temperature sintering at temperatures below 960 °C was possible, suppressing Al2TiO5 formation during firing. The dielectric characteristics, particularly the temperature coefficient of the resonant frequency (τf) and Q × f values, were improved without significantly reducing the sinterability and thermal conductivity. The dielectric properties of the developed 88Al2O3–12TiO2-based ceramic were εr: 14.7, τf: +0.8 ppm/K, and Q × f: 13,383 GHz (at ∼10 GHz) at a firing temperature of 940 °C. The thermal conductivity was 18.5 W/mK, which is the highest value for reported temperature-stable low-temperature co-fired ceramics (LTCCs). These results provide one of the key technologies for the practical application of LTCCs with superior thermal conductivities.



中文翻译:

开发出具有优异导热性的新型温度稳定的Al 2 O 3 -TiO 2基介电陶瓷,适用于LTCC应用

通过烧结开发了一种新的成分,以改善含CuO-TiO 2 -Nb 2 O 5 -Ag 2 O的低温共烧氧化铝(LTCA)的介电性能。通过用金红石TiO 2代替某些氧化铝,第二种相化合物可以从AgNbO 3变为金红石相。此外,可以在低于960℃的温度下进行低温烧结,从而抑制了烧成过程中Al 2 TiO 5的形成。介电特性,特别是谐振频率的温度系数(τ ˚F)和Q×˚F在不显着降低烧结性和热导率的情况下改善了该值。发达88Al的介电性质2 ö 3 -12TiO 2系陶瓷为ε - [R:14.7,τ ˚F:0.8 PPM / K,和Q×˚F在940的烧成温度下13383千兆赫(在〜10千兆赫): ℃。导热系数为18.5 W / mK,是所报道的温度稳定的低温共烧陶瓷(LTCC)的最高值。这些结果为具有优异导热性的LTCC的实际应用提供了关键技术之一。

更新日期:2020-10-30
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