Abstract We prepared the syndiotactic polystyrene (SPS) films such that its e crystalline phase and its channeling cavity were oriented to be parallel to the direction of the film thickness with a high regularity. Moreover, we introduced aniline molecules to these oriented cavities and successfully polymerized them to polyaniline (PANI). This is the mild and intelligent way of preparing polymer composites where the orientation and arrangements of the polymers are highly controlled. These SPS/PANI films showed the electrical conductivity to be ∼ 0.05 S/cm and the maximum molecular weight of PANI to be 30 units of aniline. Interestingly, the film thickness was found to increase by 110 to 200%. This is because some e crystalline phase is connected by the polymerization of aniline in the cavity, like sewing beads (some SPS e crystalline phase) with a thread (polymerizing PANI). The paper examined the reaction temperature of aniline in SPS films, and other properties such as conductivity, molecular weight, and yield of PANI.

中文翻译：

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串珠状管腔结晶相的连接方式：苯胺在间规聚苯乙烯高取向ε结晶相中聚合制备的新型导电聚合物复合材料

摘要 我们制备了间同立构聚苯乙烯（SPS）薄膜，使其晶相和沟道空腔以高度规则性平行于薄膜厚度方向取向。此外，我们将苯胺分子引入这些定向腔中，并成功地将它们聚合成聚苯胺 (PANI)。这是制备聚合物复合材料的温和而智能的方法，其中聚合物的取向和排列受到高度控制。这些 SPS/PANI 薄膜的导电率约为 0.05 S/cm，PANI 的最大分子量为 30 个苯胺单位。有趣的是，发现薄膜厚度增加了 110% 到 200%。这是因为一些结晶相通过苯胺在空腔中的聚合而连接，像缝纫珠（一些 SPS e 结晶相）与线（聚合 PANI）。该论文研究了苯胺在 SPS 薄膜中的反应温度，以及其他性质，如导电性、分子量和 PANI 的产率。