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Just add water: for instant and scalable conversion of metal acetates to metal-organic frameworks.
Analytical Methods ( IF 3.1 ) Pub Date : 2020-09-01 , DOI: 10.1039/d0ay01457e
Vijayan Srinivasapriyan 1
Affiliation  

MOFs are typically synthesized under severe conditions that require high pressure and temperature. Accordingly, herein we necessitated advances in their expeditious and scalable synthesis at ambient conditions. In this aspect, the Cu-BDC and Cu-BTC can now be prepared in minutes via a controlled dissolution–crystallization route with divalent metal acetate as a precursor at room temperature, and would be highly desired for industrial implementation and commercialization.

中文翻译:

只需加水即可:将乙酸金属盐立即且可扩展地转化为金属有机框架。

MOF通常在需要高压和高温的严酷条件下合成。因此,本文中我们需要在环境条件下迅速而可扩展地合成它们。在这方面,Cu-BDC和Cu-BTC现在可以在室温下以二价金属乙酸盐为前体,通过受控的溶解-结晶路线在几分钟内制备,因此在工业实施和商业化方面非常需要。
更新日期:2020-10-11
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