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A Master Equation for Photochemical Rates
Photochemistry and Photobiology ( IF 3.3 ) Pub Date : 2020-10-03 , DOI: 10.1111/php.13325
James R Bolton 1
Affiliation  

Traditionally, the general photochemical rate equation could be integrated only at two limits (high concentration and low concentration). In this paper, the general photochemical equation has been integrated to yield a master equation that is valid for any chromophore concentration. Hence, in future, data for all concentrations can be utilized in deriving the incident photon flux and/or the quantum yield for a photochemical reaction. Unfortunately, the master equation can only be used for monochromatic light sources.

中文翻译:

光化学速率的主方程

传统上,一般的光化学速率方程只能在两个极限(高浓度和低浓度)下进行积分。在本文中,通用光化学方程已被整合以产生一个对任何发色团浓度都有效的主方程。因此,将来,所有浓度的数据都可以用于推导入射光子通量和/或光化学反应的量子产率。不幸的是,主方程只能用于单色光源。
更新日期:2020-10-03
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