Pnictanes Cp*(Ph)ECl (E = As 1, Sb 2; Cp* = C₅Me₅) react with group 13 diyls LM (M = Al, Ga, In; L = HC[C(Me)N(Dip)]₂, Dip = 2,6‐iPr₂C₆H₃) with oxidative addition of the E‐Cl bond to a unique series of metalylpnictanes [L(Cl)M](Ph)ECp* (E = As, M = Al 3, Ga 4, In 5; E = Sb, M = Al 6, Ga 7, In 8). Thermal treatment of 4 and 6–8 results in homolytic E‐C bond scission with Cp* radical liberation, yielding the corresponding dipnictanes {[L(Cl)M](Ph)E}₂ (E = As, M = Ga 9; E = Sb, M = Al 10, Ga 11, In 12). Compounds 1–12 were characterized by NMR (¹H, ¹³C) and IR spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction (3–12).

中文翻译：

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尺寸问题：通过E-C键均解合成13族金属取代的二烷类化合物

Pnictanes Cp *（Ph）ECl（E = As 1，Sb 2 ; Cp * = C ₅ Me ₅）与基团13 diyls LM（M = Al，Ga，In; L = HC [C（Me）N（Dip） ）] ₂，Dip = _2,6 ‐ i Pr ₂ C ₆ H ₃），同时将E‐Cl键氧化成独特的一系列金属甲氧烷[L（Cl）M]（Ph）ECp *（E = As， M ＝ Al 3，Ga 4，In 5； E ＝ Sb，M ＝ Al 6，Ga 7，In 8。热处理4和6 – 8导致具有Cp *自由基释放的均质E-C键断裂，产生相应的二茂铁{{L（Cl）M]（Ph）E} ₂（E = As，M = Ga 9 ; E = Sb，M = Al 10，Ga 11，In 12）。化合物1 - 12由NMR（进行了表征¹ H，¹³ C）和IR光谱，元素分析，和单晶X射线衍射（3 - 12）。