ABSTRACT

Electrospinning and silver mirror reaction (SMR) were combined to synthesize silver nanowire membrane. The best sheet resistance (Rs) and transmittance (T) values reach around 15 Ω/sq and 80% on PET, 37 Ω/sq and 81% on glass, respectively. In this method, Poly(acrylonitrile – co – phenylethylene) (P(AN-S)) nanofibers act as the templates and reduction of silver on the nanofibers surface act as seeds. In SMR process, silver deposited on the surface of nanofibers and developed into silver nanowires. The membrane was characterized by scanning electron microscopy (SEM), energy dispersive spectrometer (EDS) and X-ray diffraction (XRD). The effects of spinning parameters and silver mirror reaction time on membrane properties were investigated. This process is easily controlled and it takes place at ambient condition, which gives a new opportunity for transparent conducting flexible electronics.

摘要

静电纺丝和银镜反应（SMR）相结合以合成银纳米线膜。PET 上的最佳薄层电阻 (Rs) 和透射率 (T) 值分别达到约 15 Ω/sq 和 80%，玻璃上分别达到 37 Ω/sq 和 81%。在这种方法中，聚（丙烯腈 - 共 - 苯基乙烯）（P（AN-S））纳米纤维作为模板，纳米纤维表面银的还原作为种子。在SMR工艺中，银沉积在纳米纤维表面并发展成银纳米线。通过扫描电子显微镜 (SEM)、能谱仪 (EDS) 和 X 射线衍射 (XRD) 对膜进行表征。研究了纺丝参数和银镜反应时间对膜性能的影响。这个过程很容易控制，它发生在环境条件下，