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Electrochemical Synthesis of Vinyl Sulfones by Sulfonylation of Styrenes with a Catalytic Amount of Potassium Iodide
Synlett ( IF 2 ) Pub Date : 2020-08-26 , DOI: 10.1055/s-0040-1707249
Hui Gao 1 , Pin-Hua Li 1 , Pei-Long Wang 1, 2 , Zhi-Sheng Jiang 1 , Chao Li 1 , Zhi-Ao Tian 1
Affiliation  

An electrochemical sulfonylation reaction of styrenes was developed in which sodium arylsulfinates were used as sulfonylating reagents, a catalytic amount of KI was used as a redox mediator, and Bu4NBF4 was used as the electrolyte. In addition to various styrenes, sodium arylsulfinates with either electron-donating or electron-withdrawing groups were tolerated.

中文翻译:

苯乙烯在碘化钾催化下磺酰化电化学合成乙烯基砜

开发了苯乙烯的电化学磺酰化反应,其中芳基亚磺酸钠用作磺酰化试剂,催化量的KI用作氧化还原介质,Bu4NBF4用作电解质。除了各种苯乙烯之外,还可以耐受带有给电子或吸电子基团的芳基亚磺酸钠。
更新日期:2020-08-26
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