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All-Biomass Double Network Gel: Highly Efficient Removal of Pb 2+ and Cd 2+ in Wastewater and Utilization of Spent Adsorbents
Journal of Polymers and the Environment ( IF 5.3 ) Pub Date : 2020-06-27 , DOI: 10.1007/s10924-020-01806-8
Lan Wen , Yuanmeng Zhang , Chengbin Liu , Yanhong Tang

Besides excellent adsorption performance of adsorbents, the disposal of spent adsorbents should be considered for environmental concern. In this study, a new all-biomass double network Jute/sodium alginate (Jute/SA) gel is prepared via the simple dripping technique. 80 wt% water of Jute/SA hydrogel endows the adsorbent with high permeability for heavy metal ions diffusion onto internal adsorption sites. The Jute/SA gel adsorbent can efficiently remove heavy metals from melting wastewater, especially Pb2+ and Cd2+. The adsorbent shows high adsorption capacities of 291.3 mg g−1 for Pb2+ and 149.9 mg g−1 for Cd2+ at 298 K. The adsorption equilibrium reaches within 45 min for 45 mg L−1 Cd2+ and Pb2+ using 1 g L−1 adsorbent, showing 98% removal efficiency of Pb2+ and Cd2+. Moreover, the removal efficiencies in 45 min reach up to 99.1% for Pb2+ (7.539 mg L−1) and 89.9% for Cd2+ (4.743 mg L−1) in actual melting effluent containing Zn (43.95 mg L−1), Cu (16.50 mg L−1), Mn (19.24 mg L−1), Ni (4.90 mg L−1) and Fe (33.75 mg L−1) using 1 g L−1 adsorbent. The concentrations of Pb and Cd decrease below 0.001 mg L−1 using 4 g L−1 adsorbent. Furthermore, the adsorption efficiencies for Pb2+ and Cd2+ remain above 95% in the tenth cycle, and the desorption efficiency is up to 99%. In addition, the spent Jute/SA gel was a good organic fertilizer for plant growth. This work develops an efficient and eco-friendly biomass adsorbent for the removal of heavy metals in actual wastewater.



中文翻译:

全生物质双网络凝胶:高效去除废水中的Pb 2+和Cd 2+以及利用废吸附剂

除了出色的吸附剂​​吸附性能外,出于环境考虑,还应考虑处理用过的吸附剂。在这项研究中,通过简单的滴注技术制备了一种新的全生物质双网络黄麻/海藻酸钠(Jute / SA)凝胶。80%(重量)的黄麻/ SA水凝胶赋予吸附剂高渗透性,使重金属离子扩散到内部吸附位点上。Jute / SA凝胶吸附剂可以有效地去除熔融废水中的重金属,尤其是Pb 2+和Cd 2+。291.3毫克克吸附剂显示出高的吸附容量-1对Pb 2+和149.9毫克克-12+在45分钟内在298K吸附平衡达到45毫克的L使用1 g L -1吸附剂的-1 Cd 2+和Pb 2+,显示Pb 2+和Cd 2+的去除效率为98%。此外,在45去除率分钟高达99.1%对Pb 2+(7.539毫克的L -1)和89.9%镉2+(4.743毫克的L -1在含有Zn实际熔化流出物(43.95毫克L)-1),使用1 g L -1吸附剂的Cu(16.50 mg L -1),Mn(19.24 mg L -1),Ni(4.90 mg L -1)和Fe(33.75 mg L -1)。铅和镉的浓度降至0.001 mg L -1以下使用4 g L -1吸附剂。此外,在第十个循环中,Pb 2+和Cd 2+的吸附效率保持在95%以上,并且解吸效率高达99%。另外,用过的黄麻/ SA凝胶是植物生长的良好有机肥料。这项工作开发了一种高效,环保的生物质吸附剂,用于去除实际废水中的重金属。

更新日期:2020-08-27
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