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Heat treatment effect of a hybrid consisting of SnO2 nanorod and rutile TiO2 with heteroepitaxial junction on the photocatalytic activity
Catalysis Communications ( IF 3.7 ) Pub Date : 2020-08-26 , DOI: 10.1016/j.catcom.2020.106148
Haruya Suzuki , Kenta Awa , Shin-ichi Naya , Hiroaki Tada

SnO2 nanorods were heteroepitaxially grown from rutile TiO2 (SnO2-NR#TiO2) by a hydrothermal method. This paper reports heat temperature (Tc)-dependence of the photocatalytic activity of SnO2-NR#TiO2 for the oxidation of ethanol to acetaldehyde. The activity-Tc curve exhibits a volcano-shaped curve with the maximum at Tc = 500 °C. While fusion of a bundle of thin SnO2 NRs progresses at Tc ≤ 500 °C, heating at Tc ≥ 600 °C causes their segmentation. The high activity of SnO2-NR#TiO2 with Tc = 500 °C stems from the high electron mobility in the SnO2 NRs in addition to the efficient electron transfer through the high-quality junction.



中文翻译:

SnO 2纳米棒与金红石型TiO 2异质外延键合的杂化对光催化活性的热处理作用

通过水热法从金红石型TiO 2(SnO 2 -NR#TiO 2)异质外延生长SnO 2纳米棒。本文报道了SnO 2 -NR#TiO 2对乙醇氧化为乙醛的光催化活性的热温度(T c)依赖性。活度-T c曲线呈现出火山形曲线,在T c  = 500°C时达到最大值。而薄的SnO束的融合2个卢比进展在Ť Ç  ≤500℃,在加热Ť Ç ≥600°C会导致其分割。SnO的高活性2 -NR#的TiO 2Ť ç  = 500℃从的SnO高电子迁移率茎2个除了通过高质量的结上的有效的电子转移卢比。

更新日期:2020-08-29
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