The glycidyl carbamate functional group consists of an epoxide adjacent to a carbamate or urethane. Glycidyl carbamate functional resins are compounds that have two or more glycidyl carbamate groups. Glycidyl carbamate resins can be cured through the epoxy groups with any of the typical curing agents currently used for epoxy systems such as amines, anhydrides or phenolics. An advantage of glycidyl carbamate resins is that the end user can use epoxy curing chemistry to form thermosets and obtain a polyurethane without having to handle isocyanates. This review surveys the peer‐reviewed and patent literature on glycidyl carbamate functional resins and their applications. Glycidyl carbamate compositions have been explored for use in adhesives, sealants, elastomers and coatings. In most of the reported studies, glycidyl carbamate resins offer improved adhesion, flexibility and faster curing compared to conventional epoxy resin systems, making it an attractive alternative thermosetting polymer system. © 2020 Society of Industrial Chemistry

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氨基甲酸缩水甘油酯功能树脂及其应用：综述

氨基甲酸缩水甘油酯官能团由与氨基甲酸酯或氨基甲酸酯相邻的环氧化物组成。氨基甲酸缩水甘油酯官能树脂是具有两个或更多个氨基甲酸缩水甘油酯基团的化合物。氨基甲酸缩水甘油酯树脂可通过环氧基与目前用于环氧体系的任何典型固化剂（例如胺，酸酐或酚醛树脂）一起固化。氨基甲酸缩水甘油酯树脂的一个优点是，最终用户可以使用环氧固化化学剂来形成热固性材料并获得聚氨酯，而不必处理异氰酸酯。这篇综述调查了氨基甲酸缩水甘油酯功能树脂及其应用的同行评审和专利文献。已经研究了氨基甲酸缩水甘油酯组合物用于粘合剂，密封剂，弹性体和涂料中。在大多数报告的研究中，与传统的环氧树脂体系相比，氨基甲酸缩水甘油酯树脂具有更好的粘合性，柔韧性和更快的固化速度，使其成为有吸引力的热固性聚合物体系的替代品。©2020工业化学学会