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Solution processed fabrication of silver nanowire-MXene@PEDOT: PSS flexible transparent electrodes for flexible organic light-emitting diodes
Composites Part A: Applied Science and Manufacturing ( IF 8.7 ) Pub Date : 2020-08-25 , DOI: 10.1016/j.compositesa.2020.106088
Shengchi Bai , Xingzhong Guo , Tianrui Chen , Yan Zhang , Xuyang Zhang , Hui Yang , Xiaoyu Zhao

Silver nanowire based flexible transparent electrodes (AgNW FTEs) are the most promising next-generation electrodes for flexible electronics. Novel AgNW-MXene@PEDOT:PSS (AgNW-MP) FTEs were fabricated by solution process, and flexible organic light emitting diodes (FOLED) were further demonstrated. Interactions between Ti3C2Tx MXene and PEDOT:PSS allow a high conductive quinoid state of PEDOT:PSS and AgNW-MP FTEs achieve a sheet resistance of 17 Ω/sq and transmittance of 97.6%. MP21 hybrids (mass ratio of 2:1) as nanowelding materials improve surface roughness (RMS roughness value of 8.2 nm) and enhance stability resisting 5000 cycles of bending or H2S gas corrosion. High efficiency FOLEDs with large emission area using commercial materials and structure were demonstrated, achieving a maximum external quantum efficiency of 25.9% and luminous efficiency over 21 cd/A due to better optoelectrical properties and higher work function. It suggests an important step toward producing commercial AgNW based hybrid FTEs for flexible OLEDs and other flexible electronics.



中文翻译:

银纳米线-MXene @ PEDOT的固溶处理制造:用于柔性有机发光二极管的PSS柔性透明电极

基于银纳米线的柔性透明电极(AgNW FTE)是柔性电子产品最有希望的下一代电极。通过溶液法制备了新型AgNW-MXene @ PEDOT:PSS(AgNW-MP)FTE,并进一步展示了柔性有机发光二极管(FOLED)。Ti 3 C 2 T x MXene与PEDOT:PSS之间的相互作用允许PEDOT:PSS和AgNW-MP FTE的高导电醌型态实现17Ω/ sq的薄层电阻和97.6%的透射率。MP21杂化材料(质量比为2:1)作为纳米焊接材料可改善表面粗糙度(RMS粗糙度值为8.2 nm)并增强稳定性,可抵抗5000次弯曲或H 2循环S气体腐蚀。演示了使用商用材料和结构的具有大发射面积的高效FOLED,由于具有更好的光电性能和更高的功函,其实现了25.9%的最大外部量子效率和超过21 cd / A的发光效率。这表明朝着生产用于柔性OLED和其他柔性电子产品的商用基于AgNW的混合FTE迈出了重要的一步。

更新日期:2020-08-25
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