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Recent advances in catalytic oxidation of 5-hydroxymethylfurfural
Molecular Catalysis ( IF 4.6 ) Pub Date : 2020-08-23 , DOI: 10.1016/j.mcat.2020.111133
Deyang Zhao , Ting Su , Yantao Wang , Rajender S. Varma , Christophe Len

5-Hydroxymethylfurfural (HMF) has been considered as one of the most promising versatile biomass based platform molecules. This review discusses recent advances in catalytic oxidation of HMF towards 2, 5-furandicarboxylic acid (FDCA) as well as other HMF oxidation intermediates: 2,5-diformylfuran (DFF), 5-hydroxymethyl-2-furancarboxylic acid (HMFCA), 5-formyl-2-furancarboxylic acid (FFCA) deploying noble, non-noble, metal-free and biocatalytic systems in conventional batch protocols; reaction mechanisms and the reaction conditions are well deliberated. Selective HMF downstream oxidation products are obtained via catalyst modifications such as the nature of metal, preparative method as well the property of deployed support. HMF oxidation, an important and integral biomass-based valorization process towards valuable chemicals, deserves more attention.



中文翻译:

5-羟甲基糠醛催化氧化的最新进展

5-羟甲基糠醛(HMF)被认为是最有前途的基于生物质的多功能平台分子之一。这篇综述讨论了HMF催化氧化为2,5-呋喃二甲酸(FDCA)以及其他HMF氧化中间体的最新进展:2,5-二甲酰呋喃(DFF),5-羟甲基-2-呋喃羧酸(HMFCA),5 -甲酰基-2-呋喃甲酸(FFCA)在常规批处理方案中部署了贵金属,非贵金属,无金属和生物催化系统;反应机理和反应条件经过深思熟虑。选择性HMF下游氧化产物可通过催化剂的改性,例如金属的性质,制备方法以及展开载体的性质。HMF氧化是一种重要的,不可或缺的,基于生物质的增值工艺,可用于有价值的化学物质,值得更多关注。

更新日期:2020-08-23
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