Solution processed thin chalcogenide films gain attention due to their interesting optical properties and simplicity of the deposition. The influence of the aliphatic chain length in primary amines used for As₃₃S₆₇ thin films deposition by spin-coating and their subsequent characterization had been studied in this paper, particularly films prepared from solutions based on n-propylamine, n-butylamine, n-pentylamine and n-hexylamine were investigated. As-prepared thin films were annealed at temperatures below glass T_g. Results gave evidence that variety in physical and chemical properties of studied amines influences required conditions of deposition process of the thin film only (such as source glass dissolution time, thin film thickness, thickness shrinkage). The structure, optical properties, surface roughness, organic residual content and chemical resistance of deposited thin films are not significantly influenced by used amine but mostly by the post-deposition annealing temperature. Thin films composition remains uninfluenced by neither used amine nor the annealing temperature.

溶液处理的硫族化物薄膜由于其有趣的光学特性和沉积的简单性而备受关注。本文研究了脂族链长对旋涂As ₃₃ S ₆₇薄膜所用伯胺的影响及其后续表征，特别是由基于正丙胺，正丁胺，研究了戊胺和正己胺。所制备的薄膜在低于玻璃化温度T _g的温度下退火。结果提供了证据，表明所研究胺的理化性质的不同仅影响薄膜沉积过程的必要条件（例如源玻璃的溶解时间，薄膜厚度，厚度收缩率）。沉积的薄膜的结构，光学性能，表面粗糙度，有机残留含量和耐化学性不受使用的胺的影响很大，但主要受沉积后退火温度的影响。薄膜组成不受使用的胺或退火温度的影响。