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Corrosion inhibitor by a polymerizable columnar mesogen based on hexabenzocoronene derivative
Journal of the Chinese Chemical Society ( IF 1.8 ) Pub Date : 2020-08-21 , DOI: 10.1002/jccs.202000168
Yu‐Te Liu, Han‐Wen Kuo, Chi‐Wei Cheng, Wen‐Ti Wu, Kuan‐Ying Chen, Jui‐Ming Yeh, Hsiu‐Hui Chen

A hexa‐peri‐hexabenzocoronene derivative (HBC‐1,2,4‐Ph‐DA‐C12) with the central HBC core tethered with three diacetylene (DA)‐containing chains and three saturated alkyl chains was applied for the anticorrosion of an iron surface. This compound, which exhibits a columnar liquid crystalline phase, could be polymerized by ultraviolet irradiation through reactions between the DA units. This polymer coating exhibited a good anticorrosion property with good hydrophobicity (contact angle [CA] ~ 84°–105°) and excellent mechanical property. It showed a high resistance of 149 kΩ/cm2, much higher than that of known anticorrosion materials.

中文翻译:

基于六苯并并苯衍生物的可聚合柱状介晶的缓蚀剂

六--hexabenzocoronene衍生物(HBC-1,2,4- PH-DA-C 12)与所述中央芯HBC拴具有三个二乙炔(DA)含链和三个饱和烷基链涂敷了用于的防腐铁表面。这种显示出柱状液晶相的化合物可以通过DA单元之间的反应通过紫外线照射而聚合。这种聚合物涂层具有良好的防腐性能和良好的疏水性(接触角[CA]〜84°–105°)和出色的机械性能。它显示出149kΩ/ cm 2的高电阻,远高于已知的防腐材料。
更新日期:2020-09-24
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