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Preparation of ruthenium-functionalized microgels through the intermolecular crosslinking of two functionalized polymers within droplets and study of their chemical/ photo-active behaviors
Polymer Degradation and Stability ( IF 5.9 ) Pub Date : 2020-08-22 , DOI: 10.1016/j.polymdegradstab.2020.109345
Yuandu Hu , Jason Tresback , Juan Pérez-Mercader

Ruthenium-functionalized microgels were prepared with the combination of microfluidics-based droplet template approach and the direct crosslinking of two types of functionalized polymers within the droplet “microreactor”. The microgels displayed a variety of properties, including the catalytic capability for Belousov-Zhabotinsky reaction, white light induced structural memory behavior and monochromatic lights triggered photolysis and structural degradation behaviors. The photo degradation mechanism is also proposed and further verified by multiple characterization methods.



中文翻译:

通过液滴内两种官能化聚合物的分子间交联制备钌官能化微凝胶,并研究其化学/光敏行为

通过基于微流体的液滴模板方法和液滴“微反应器”内两种类型的官能化聚合物的直接交联的组合,制备了钌官能化的微凝胶。这些微凝胶显示出各种特性,包括对Belousov-Zhabotinsky反应的催化能力,白光诱导的结构记忆行为以及单色光触发的光解和结构降解行为。还提出了光降解机理并通过多种表征方法进一步验证。

更新日期:2020-08-25
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