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Rhodium Catalysts with a Chiral Cyclopentadienyl Ligand Derived from Natural R‐Myrtenal
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-08-20 , DOI: 10.1002/ejoc.202001029
Roman A. Pototskiy 1 , Andrey V. Kolos 1 , Yulia V. Nelyubina 1 , Dmitry S. Perekalin 1, 2
Affiliation  

Rhodium complex with a new chiral cyclopentadiene was synthesized from the natural (R)‐myrtenal and tested as a catalyst in C–H activation reaction providing dihydroisoquinolinones with high yields and moderate enantioselectivity.
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中文翻译:

衍生自天然R-Myrtenal的手性环戊二烯基配体的铑催化剂

铑与新型手性环戊二烯的铑配合物是由天然(R)-Myrtenal合成的,并在CH-H活化反应中作为催化剂进行测试,可提供高收率和中等对映选择性的二氢异喹啉酮。
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更新日期:2020-10-02
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