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Synthesis and characterization of three ternary samarium(III) complexes and their optical properties
Spectroscopy Letters ( IF 1.7 ) Pub Date : 2020-08-19 , DOI: 10.1080/00387010.2020.1806081
Archana Chauhan 1 , Sheetal Lohra 2 , Ritu Langyan 1
Affiliation  

Abstract Three ternary samarium(III) complexes with 6-methyl-4-oxo-4H-1-benzopyran-3-carboxaldehyde, 4-methyl-1,10-Phenanthroline, and 2,2′-Biquinoline and Bathocuproine have been prepared and characterized. The complexes exhibit crystalline character and excellent thermal stability. On irradiation with ultraviolet radiation, the complexes display characteristic emission peaks of samarium(III) ion. The color coordinates, decay curves, and quantum yield have been discussed in detail. The investigations demonstrate that the synthesized complexes might be practically useful in bio-assays, electroluminescent devices, and liquid lasers due to their fascinating optical properties.

中文翻译:

三种三元钐(III)配合物的合成与表征及其光学性质

摘要 制备了三种三元钐 (III) 与 6-methyl-4-oxo-4H-1-benzopyran-3-carboxaldehyde、4-methyl-1,10-Phenanthroline、2,2'-Biquinoline 和 Bathocuproine 的配合物,并表征。该配合物表现出结晶特性和优异的热稳定性。在用紫外线辐射照射时,配合物显示出钐 (III) 离子的特征发射峰。已经详细讨论了颜色坐标、衰减曲线和量子产率。研究表明,合成的复合物由于其迷人的光学特性,可能在生物测定、电致发光器件和液体激光器中具有实际用途。
更新日期:2020-08-19
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