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Synthesis, Crystal Structure, Luminescence, and Nonlinear Optical Properties of 2-[(E)-[[4-[2-(4-Methoxyphenyl)ethynyl]phenyl] imino]methyl]-4- [(E)-phenyldiazenyl]phenol
Letters in Organic Chemistry ( IF 0.8 ) Pub Date : 2020-07-31 , DOI: 10.2174/1570178617666200207104157
Sagar Subhash Mohite 1 , Aditya Babasaheb Patil-Deshmukh 1 , Sanjay Shamrao Chavan 1
Affiliation  

2-((E)-((4-((4-methoxyphenyl)ethynyl)phenyl)imino)methyl-4-((E)phenyldiazenyl)phenol (1) have been synthesized and characterized. X-ray single crystal diffraction study of the compound 1 reveal a monoclinic structure. Room temperature luminescence is observed for 1 in CH2Cl2 solution due to π* → π transition. The SHG efficiency by Kurtz powder technique indicating the compound 1 displayed the second harmonic generation (SHG) property.



中文翻译:

2-[(E)-[[4- [2-(4-甲氧基苯基)乙炔基]苯基]亚氨基]甲基] -4-[(E)-苯基二氮烯基]苯酚的合成,晶体结构,发光和非线性光学性质

X-射线单晶衍射研究合成了2-((E)-((4​​-((4-甲氧基苯基)乙炔基)苯基)亚氨基)甲基-4-((E)苯基二氮烯基)苯酚(1)。化合物1的化合物显示单斜晶结构,由于π*→π跃迁,在CH 2 Cl 2溶液中观察到室温下的发光,通过库尔兹粉末技术的SHG效率表明化合物1显示出二次谐波(SHG)性质。

更新日期:2020-07-31
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