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Organic Resonance Materials: Molecular Design, Photophysical Properties, and Optoelectronic Applications.
The Journal of Physical Chemistry Letters ( IF 5.7 ) Pub Date : 2020-08-17 , DOI: 10.1021/acs.jpclett.0c01571
He Jiang 1 , Yang Cao 1 , Qingqing Yang 1 , Lijie Xian 1 , Ye Tao 1 , Runfeng Chen 1 , Wei Huang 1, 2
Affiliation  

Organic optoelectronic molecules with resonance effects are a striking class of functional materials that have witnessed booming progress in recent years. Various resonances induced by particularly constructed molecular structures can effectively influence key photophysical processes to afford particular optoelectronic properties of the organic resonance materials. The charge transport behaviors were tuned to be dynamic and self-adaptive; emission spectra were made to be very narrow with high color purity; optical bandgaps were significantly reduced, and intersystem crossing was greatly promoted. Therefore, great success has been achieved in various optoelectronic devices by using organic resonance materials to function as smart host materials with high triplet energies, highly luminescent emitters with high quantum yields and narrow emission bands, efficient organic afterglow molecules, and sensitive fluorescent probes. In this Perspective, material design principles, molecular structures and properties, and device performance of organic resonance materials are highlighted and future directions and challenges for this series of amazing materials are discussed.

中文翻译:

有机共振材料:分子设计,光物理性质和光电应用。

具有共振效应的有机光电分子是功能性材料中的一类,近年来已见证了它们的蓬勃发展。由特别构造的分子结构引起的各种共振可以有效地影响关键的光物理过程,以提供有机共振材料的特定光电特性。电荷传输行为被调整为动态的和自适应的。发射光谱非常窄,色纯度高;光学带隙显着降低,并且大大促进了系统间交叉。因此,通过使用有机共振材料充当具有高三重态能量的智能主体材料,在各种光电设备中都取得了巨大的成功,具有高量子产率和窄发射带的高发光发射体,有效的有机余辉分子和敏感的荧光探针。在本“观点”中,重点介绍了有机共振材料的材料设计原理,分子结构和性能以及器件性能,并讨论了该系列惊人材料的未来方向和挑战。
更新日期:2020-09-18
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