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Upconversion properties of Gd-based ceramics, attached into polystyrene films
Journal of the Australian Ceramic Society ( IF 1.9 ) Pub Date : 2020-08-18 , DOI: 10.1007/s41779-019-00378-8
A. Carro-Gastélum , S. Carmona-Téllez , S. Loera-Serna , L. Mariscal-Becerra , H. Murrieta S , G. Alarcón-Flores , C. Falcony

Tm3+- and Yb3+-doped lithium-gadolinium oxide (Li-Gd2O3) ceramics, prepared by the simple evaporation technique, were incorporated into polystyrene (PS) films (as recycled Styrofoam). A study of the upconversion (UC) emission from Tm3+ as well as Yb3+ ions was performed under continuous wave excitation of a 980-nm laser, for both powder and PS film samples. High-intensity light emissions (UC) were observed at 476, 488, and 665 nm, associated with inter electronic energy state transitions of the Tm3+ ion, from 1D2 to 3F4, 1G4 to 3H6, and 3F3 to 3H6, respectively. Yb3+ presence makes possible the thulium blue emission in the UC luminescence because it acts as a sensitizer under 980-nm excitation. Lithium is used as part of the host lattice (Lix-Gd2-xO3; 0 ≤ x ≥ 1) in order to achieve a greater crystallinity as Li+ acts as fluxing agent. The PS films remain highly transparent in the light’s visible region even after the incorporation of the ceramic particles (around 80% T).



中文翻译:

附着在聚苯乙烯薄膜中的G基陶瓷的上转换特性

通过简单的蒸发技术制备的掺有Tm 3+和Yb 3+的锂氧化d锂(Li-Gd2O3)陶瓷被掺入到聚苯乙烯(PS)薄膜中(作为回收的聚苯乙烯泡沫塑料)。对于粉末和PS薄膜样品,在980 nm激光的连续波激发下,对Tm 3+和Yb 3+离子的上转换(UC)发射进行了研究。高强度的光发射(UC)在476,488,和665nm处观察到,与TM的帧间电子能量状态跃迁相关联3+离子,从1 D2至3 F4,1个G4至3 H6,和3 F3至3H6分别。Yb 3+的存在使UC发光中的blue蓝色发射成为可能,因为它在980 nm激发下起敏化剂的作用。锂作为主晶格的一部分(LIX-的Gd2-xO3; 0≤  X  ≥1),以实现更大的结晶度如Li +作为助熔剂。即使掺入了陶瓷颗粒(T含量约为80%),PS膜仍在光的可见区域保持高度透明。

更新日期:2020-08-18
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