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Selective Reduction and Dihydroxylation of
Heterocycles ( IF 0.6 ) Pub Date : 2020-07-17 , DOI: 10.3987/com-20-s(k)15 Hiromichi Fujioka , Kenta Morita , Kenichi Murai , Mitsuhiro Arisawa
Heterocycles ( IF 0.6 ) Pub Date : 2020-07-17 , DOI: 10.3987/com-20-s(k)15 Hiromichi Fujioka , Kenta Morita , Kenichi Murai , Mitsuhiro Arisawa
Two-way discriminative conversion, reduction and dihydroxylation of α,β-unsaturated esters were achieved in the presence of enals using two phosphonium salts as in situ protecting groups. Furthermore, a pot-economical one-pot synthesis of a tetrahydrofuran derivative was achieved.
中文翻译:
选择性还原和二羟基化
在使用两种phospho盐作为原位保护基的烯醛存在下,实现了α,β-不饱和酯的双向鉴别转化,还原和二羟基化。此外,实现了四氢呋喃衍生物的锅内经济的一锅合成。
更新日期:2020-09-08
中文翻译:
选择性还原和二羟基化
在使用两种phospho盐作为原位保护基的烯醛存在下,实现了α,β-不饱和酯的双向鉴别转化,还原和二羟基化。此外,实现了四氢呋喃衍生物的锅内经济的一锅合成。