The molecular surface imprinted graft copolymer of metal-organic framework MOF-5 with methacrylic acid were prepared by free radical polymerization with dibutyl phthalate as the template molecule using initiator of azobisisobutyronitrile as adsorption system. The prepared MIPs@MOF-5 were characterized by fourier transform infrared spectroscopy, scanning electron microscopy, Brunner−Emmet−Teller measurements, adsorption isotherms, kinetics and selectivity experiments, which showed higher specificity, sensitivity, stability, and better adsorption performance. The results suggested that MIPs@MOF-5 had two sites of adsorption behavior and can recognize sensitively and selectively the template molecules. Moreover, the MIPs@MOF-5 was successfully applied to the analysis of tap water sample.

以偶氮二异丁腈为引发剂，以邻苯二甲酸二丁酯为模板分子，通过自由基聚合制备了金属有机骨架MOF-5与甲基丙烯酸的分子表面印迹接枝共聚物。通过傅立叶变换红外光谱，扫描电子显微镜，Brunner-Emmet-Teller测量，吸附等温线，动力学和选择性实验对制备的MIPs @ MOF-5进行了表征，显示出更高的特异性，灵敏度，稳定性和更好的吸附性能。结果表明，MIPs @ MOF-5具有两个吸附行为，可以灵敏和选择性地识别模板分子。此外，MIPs @ MOF-5已成功应用于自来水样品的分析。