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Creep behavior and post-creep thermoelectric performance of the n-type Skutterudite alloy Yb0.3Co4Sb12
Journal of Materiomics ( IF 9.4 ) Pub Date : 2020-08-13 , DOI: 10.1016/j.jmat.2020.07.012
Muath M. Al Malki , Xun Shi , Pengfei Qiu , G. Jeffrey Snyder , David C. Dunand

Upon uniaxial compressive loading at 500 °C (T/Tm = 0.67, where Tm is the absolute melting point), the n-type Skutterudite alloy Yb0.3Co4Sb12 deforms plastically by creep via a power-law, with a stress exponent ∼3 consistent with dislocation viscous glide. An activation energy of 171 kJ/mol is measured over the temperature range of 500–587 °C (T/Tm = 0.67–0.75) at a stress of 30 MPa. Yb0.3Co4Sb12 is ductile at 500 °C, exhibiting a compressive strain of 25% when subjected to stresses ranging from 22 to 90 MPa for up to 28 days. Among the thermoelectric materials tested so far for creep, Yb0.3Co4Sb12 exhibits a creep resistance intermediate between low-melting (Bi2Te3, TAGS-85) and high-melting thermoelectrics (Mg2Si and ZrNiSn). A relatively modest drop in the figure of merit zT, from 0.67 to 0.52, is displayed by Yb0.3Co4Sb12 after accumulating 3.7% compressive creep strain at 500 °C, mostly due to a drop in electrical conductivity.



中文翻译:

n型Skutterudite合金Yb 0.3 Co 4 Sb 12的蠕变行为和蠕变后热电性能

在500°C的单轴压缩载荷下(T / T m  = 0.67,其中T m为绝对熔点),n型Skutterudite合金Yb 0.3 Co 4 Sb 12通过幂律蠕变塑性变形,其屈服强度为应力指数〜3与位错粘性滑移一致。在500-587°C(T / T m  = 0.67-0.75)的温度范围内,在30 MPa的应力下测得的活化能为171 kJ / mol 。Yb 0.3 Co 4 Sb 12在500°C时易延展,当承受22至90 MPa的应力达28天时,表现出25%的压缩应变。在迄今为止测试的蠕变热电材料中,Yb 0.3Co 4 Sb 12在低熔点(Bi 2 Te 3,TAGS-85)和高熔点热电材料(Mg 2 Si和ZrNiSn)之间表现出耐蠕变性。Yb 0.3 Co 4 Sb 12在500°C下累积了3.7%的压缩蠕变应变后,品质因数zT的相对适度的下降从0.67下降至0.52 ,这主要是由于电导率的下降。

更新日期:2020-10-05
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