A novel coordination polymer (CP) based on Zn(II) of [Zn(tptc)_0.5(bpy)(H₂O)]_n (1) was synthesized through utilizing the 2,2′-bipyridine (bpy) chelating N donors and p-terphenyl-2,2′’,5′’,5′’’-tetracarboxylate acid (H₄tptc) as the co-ligands. The measurements of the fluorescence were implemented for the complex 1 in solution and solid state, and the result reveals that 1 has a strong fluorescence and it is a sensory material with great development space to determine the trace Cr₂O₇²⁻ (with the detection limit of 36 ppb) in the water solutions via applying the fluorescence quenching effect. As the common disease in the orthopedic nursing, the deep vein thrombosis was the objective in this research. The weigh and length of the thrombus in the animals were measured and analyzed. In addition to this, the inflammatory response in the deep vein thrombosis animal was evaluated by RT-PCR. Molecular docking results indicate that only the carboxyl group could provide polar oxygen atoms for the formed hydrogen bonds to the protein.

中文翻译：

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荧光 Zn(II) 配位聚合物：水中 Cr2O72- 的灵敏检测和骨科护理中深静脉血栓形成的预防活性。

利用 2,2'-联吡啶 (bpy) 螯合 N 供体合成了一种基于 Zn(II) [Zn(tptc) _0.5 (bpy)(H ₂ O)] _n ( 1 ) 的新型配位聚合物 (CP)和p -terphenyl-2,2'',5'',5'''-tetracarboxylate acid (H ₄ tptc) 作为共配体。对配合物1的溶液和固态荧光进行了测量，结果表明1具有强烈的荧光，是一种具有很大发展空间的传感材料，可用于测定痕量Cr ₂ O ₇ ²⁻（检测限为 36 ppb）通过应用荧光猝灭效应在水溶液中。深静脉血栓形成作为骨科护理中的常见病，是本次研究的对象。测量和分析动物体内血栓的重量和长度。除此之外，还通过 RT-PCR 评估了深静脉血​​栓形成动物的炎症反应。分子对接结果表明，只有羧基可以为与蛋白质形成的氢键提供极性氧原子。