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Fabrication of Cr2S3-GO-TiO2 composite with high visible-light-driven photocatalytic activity on degradation of organic dyes
Chemical Physics ( IF 2.3 ) Pub Date : 2020-08-12 , DOI: 10.1016/j.chemphys.2020.110950
Jaafar Hasan , Haidi Li , Guang Tian , Chuanguang Qin

Ternary compound photocatalyst (Cr2S3-GO/TiO2 composite) was prepared by combining graphene oxide (GO) and titanium oxide (TiO2) via sol–gel technique. This synthesized composite was characterized by various methods of analysis (XPS, XRD, SEM, EDX, BET, TGA and TEM). The as-synthesized composite exhibited enhanced photocatalytic performance and degradation rate yielded 98.3, 96.6 and 86.3% on methylene blue, rhodamine B and methyl orange, respectively, under the visible light for 120 min. Cr2S3-GO/TiO2 composite achieved the best photocatalytic activity with 0.3 mol of TiO2. This might be due to the collaborative interaction between increased defects of graphene oxide and photocatalytic effect of Cr2S3. Kinetic model data best fitted with pseudo-first-order model with regression coefficient values of R2 ≥ 0.96. This provides a good opportunity for increased photocatalytic activity in the treatment of wastewater from organic pollutants.



中文翻译:

可见光驱动的高降解有机染料降解Cr 2 S 3 -GO-TiO 2复合材料的制备

通过溶胶-凝胶技术将氧化石墨烯(GO)和氧化钛(TiO 2)结合制备三元复合光催化剂(Cr 2 S 3 -GO / TiO 2复合材料)。通过各种分析方法(XPS,XRD,SEM,EDX,BET,TGA和TEM)对合成的复合材料进行了表征。合成后的复合材料在可见光下持续120分钟,对亚甲基蓝,若丹明B和甲基橙的光催化性能增强,降解率分别为98.3%,96.6%和86.3%。Cr 2 S 3 -GO / TiO 2复合材料以0.3 mol的TiO 2达到了最佳的光催化活性。。这可能是由于氧化石墨烯缺陷增加与Cr 2 S 3的光催化作用之间的协同相互作用。动力学模型数据最好装有有R的回归系数的值的伪一阶模型2  ≥0.96。这为提高光催化活性处理有机污染物废水提供了一个很好的机会。

更新日期:2020-08-21
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