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New Organosilicon Salts and Ionic Liquids Based on 2-Thiobenzazolium Cations
Russian Journal of General Chemistry ( IF 0.9 ) Pub Date : 2020-08-10 , DOI: 10.1134/s1070363220070105
L. V. Zhilitskaya , N. О. Yarosh , L. G. Shagun , I. А. Dorofeev

Abstract

The base-free reactions of 2-thiobenzothiazole, -imidazole, and -oxazole with iodomethyldimethyl(ethynyl)- and (phenyl)silanes have been studied. Depending on the reaction conditions, organosilicon acetylenic, organosilicon aromatic, or siloxane thiobenzazolium iodides and polyiodides have been synthesized and identified using the data of NMR, IR, and UV spectroscopy.


中文翻译:

基于2-噻唑鎓阳离子的新型有机硅盐和离子液体

摘要

已经研究了2-硫代苯并噻唑,-咪唑和-恶唑与碘甲基二甲基(乙炔基)-和(苯基)硅烷的无碱反应。根据反应条件,已经合成并使用NMR,IR和UV光谱数据鉴定并鉴定了有机硅炔属,有机硅芳族或硅氧烷硫代苯并碘鎓和聚碘化物。
更新日期:2020-08-10
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