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Non-isothermal conversion of wheat husk and low-density polyethylene for energy dense fuel production
Biomass Conversion and Biorefinery ( IF 4 ) Pub Date : 2020-08-11 , DOI: 10.1007/s13399-020-00951-3
P. Rajkumar , Murugavelh Somasundaram

Thermochemical conversion of wheat husk biomass, LDPE and its blends was performed in a fixed bed reactor at 500 °C. The fixed bed reactor was designed and developed for pyrolysis reaction that can withstand up to 1000 °C. Based on thermogravimetric analysis (TGA) profile, the experiment was carried out at different temperature ranges from 350 to 550 °C to optimize the temperature for higher oil production. The study was conducted to investigate the co-pyrolysis effect on oil yield by adding LDPE as a blend with wheat husk at 1:0, 1:1, 2:1, 1:2 and 0:1 at 500 °C. It is noted that the blend of 1:2 found to produce more liquid component compared with other blends. Addition of LDPE drastically increases the calorific value in the oil component; meanwhile, it also decreases the oxygenated group present in the oil sample. Co-pyrolysis obtained is then analysed with GC-MS and FTIR to elucidate the functional group present in the oil sample. Calorific value of wheat husk and LDPE was found around 22.91 MJ kg−1 and 18.43 MJ kg−1, where the calorific value of the oil for the blends of 0:1, 1:1, 2:1, 1:2 and 1:0 were found to be 27.99 MJ kg−1, 28.09 MJ kg−1, 28.38 MJ kg−1, 29.45 MJ kg−1, 30.64 MJ kg−1, respectively. This attributes that co-pyrolytic oil tends to produce fuel with higher energy content.



中文翻译:

麦壳和低密度聚乙烯的非等温转化以生产高能燃料

小麦皮生物质,LDPE及其混合物的热化学转化是在500°C的固定床反应器中进行的。固定床反应器的设计和开发可承受高达1000°C的热解反应。根据热重分析(TGA)曲线,在350至550°C的不同温度范围内进行了实验,以优化温度以提高产油量。通过在500°C下以1:0、1:1、2:1、1:2和0:1加入LDPE与小麦皮的混合物来研究共热解对油品产量的影响。注意,与其他共混物相比,发现1:2的共混物产生更多的液体组分。LDPE的添加极大地增加了油成分中的热值。同时,它也减少了油样中存在的氧化基团。然后用GC-MS和FTIR分析获得的共热解,以阐明油样品中存在的官能团。发现小麦皮和低密度聚乙烯的发热量约为22.91 MJ千克-1和18.43公斤MJ -1,其中油为0共混物的热值:1,1:1,2:1,1:2和1:0被发现是27.99 MJ千克-1,28.09 MJ千克-1,28.38 MJ千克-1,29.45 MJ千克-1,30.64 MJ千克-1,分别。这归因于共热解油倾向于产生具有更高能量含量的燃料。

更新日期:2020-08-11
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