Journal of Non-Crystalline Solids ( IF 3.5 ) Pub Date : 2020-08-10 , DOI: 10.1016/j.jnoncrysol.2020.120353 Alaa M. Abd-Elnaiem , S. Moustafa , A.M. Abdelraheem , M.A. Abdel-Rahim , A.Z. Mahmoud
This study reposts the influence of annealing temperature (TA) on structural and optical properties of ~150 nm thick Ge20Se70Sn10 films. Amorphous Ge20Se70Sn10 films were prepared via thermal evaporation of bulk Ge20Se70Sn10 glass. The films were then annealed between 503 and 703 K leading to the formation of Sn0.5Ge0.5Se and Ge4Se9 phases. For samples annealed at TA ≥ 653 K, Sn0.5Ge0.5Se phase decomposed to from Ge4Se9 phase . Based on the reflectance R(λ) and transmittance T(λ) studies, various optical constants such as the refractive index and extinction coefficient, real and imaginary of dielectric constants among others were investigated. Linear parameters such as the optical band gap decreased (~0.94 eV) as the annealing temperature increased while the Urbach energy reveals contrasting behavior. The oscillator energy and the dispersion energy decreased with increasing TA. Other electronic parameters such as the Penn gap, electronic polarizability, Fermi energy, VELF, and SELF functions are significantly influenced by TA.
中文翻译:
退火对光电应用Ge 20 Se 70 Sn 10薄膜的结构和光学性能的影响
本研究转播退火温度(影响Ť甲)上〜150nm厚的Ge的结构和光学性质20硒70的Sn 10薄膜。通过块状Ge 20 Se 70 Sn 10玻璃的热蒸发来制备非晶Ge 20 Se 70 Sn 10膜。然后将薄膜在503和703 K之间退火,从而形成Sn 0.5 Ge 0.5 Se和Ge 4 Se 9相。在退火样品 Ť甲 ≥653 K,Sn的0.5葛0.5Se从Ge 4 Se 9相分解为Se 。基于反射率R(λ)和透射率T(λ)的研究,研究了各种光学常数,例如折射率和消光系数,介电常数的实部和虚部。线性参数(如光学带隙)随着退火温度的升高而降低(约0.94 eV),而Urbach能量则表现出相反的行为。振荡器能量和色散能量随着T A的增加而减小。诸如Penn间隙,电子极化率,费米能量,VELF和SELF功能等其他电子参数受以下因素的影响很大牛逼一个。