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Broadband flat near-infrared emission and energy transfer of Pr3+–Er3+–Yb3+ tri-doped niobate tellurite glasses
Journal of Non-Crystalline Solids ( IF 3.5 ) Pub Date : 2020-08-09 , DOI: 10.1016/j.jnoncrysol.2020.120335
Ho Kim Dan , Nguyen Minh Ty , Vu Hang Nga , Doan Thi Phuc , Anh-Luan Phan , Dacheng Zhou , Jianbei Qiu

The near-infrared (NIR) emission and energy transfer (ET) of Pr3+–Er3+–Yb3+ tri-doped in TeO2–Nb2O5–BaO–La2O3 niobate tellurite glasses under the excitation of a 980 nm laser diode (LD) were investigated. A broadband flat NIR emission of Pr3+–Er3+–Yb3+ tri-doped was observed within the range of 1250 to 1650 nm with a full-width at half-maximum (FWHM) of about 300 nm which covered the whole O-, E-, S-, C- and (C+L)- bands. The role of Yb3+ for enhancing the intensity of NIR emissions has also been examined. Remarkably, the analysis results on the DTA curve exhibited the good thermal stability of TeO2–Nb2O5–BaO–La2O3 niobate tellurite glasses in this study with the average value of ΔT = 196°C. The GPr(λ), GEr(λ) gain coefficient spectra of Pr3+ and Er3+, respectively in the TNBL-0P0.1E0Y (Er3+-single-doping) and the TNBL-0.8P0E0Y (Pr3+-single-doping), are determined. Besides, the mechanism of ET processes between Pr3+, Er3+, and Yb3+ was proposed and discussed.



中文翻译:

宽带的镨平近红外发射和能量转移3+ -Er 3+ -Yb 3+三掺杂铌酸碲酸盐玻璃

近红外(NIR)辐射和能量转移(ET)镨3+ -Er 3+ -Yb 3+三掺杂的TeO 2 -Nb 2 ö 5 -BaO-的La 2 ö 3铌酸碲酸盐玻璃的激发下研究了980 nm激光二极管(LD)的尺寸。的宽带平坦NIR发射镨3+ -Er 3+ -Yb 3+ 1250的范围内,观察到1650nm的三掺杂有全宽,其覆盖了整个的约300nm的半最大值(FWHM) O,E,S,C和(C + L)-频段。Yb 3+的作用还研究了增强NIR发射强度的方法。值得注意的是,在本研究中,DTA曲线的分析结果显示了TeO 2 -Nb 2 O 5 -BaO-La 2 O 3铌酸碲玻璃的良好热稳定性,其平均值为ΔT= 196°C。对于g(λ),G(λ)Pr中增益系数频谱3+和Er 3+,分别在TNBL-0P0.1E0Y(二3+ -单掺杂)和TNBL-0.8P0E0Y(镨3 + -单掺杂)。此外,Pr 3+,Er 3+和Yb之间的ET过程机理提出并讨论了3+

更新日期:2020-08-09
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