当前位置:
X-MOL 学术
›
Russ. J. Coord. Chem.
›
论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Unexpected Participation of the Carbonate Anion in the Assembly of Hexanuclear Cadmium(II) Trimethylacetate Complex
Russian Journal of Coordination Chemistry ( IF 1.9 ) Pub Date : 2020-08-08 , DOI: 10.1134/s1070328420080047 G. N. Kuznetsova , D. S. Yambulatov , M. A. Kiskin , N. V. Gogoleva , M. A. Shmelev , A. A. Sidorov , I. L. Eremenko
中文翻译:
碳酸根阴离子意外地参与六核三甲基乙酸镉(II)配合物的组装
更新日期:2020-08-08
Russian Journal of Coordination Chemistry ( IF 1.9 ) Pub Date : 2020-08-08 , DOI: 10.1134/s1070328420080047 G. N. Kuznetsova , D. S. Yambulatov , M. A. Kiskin , N. V. Gogoleva , M. A. Shmelev , A. A. Sidorov , I. L. Eremenko
Abstract
A new unusual molecular complex [Cd6(CO3)(Piv)10(Phen)2] (I) was prepared by the reaction of cadmium(II) trimethylacetate, Cd(Piv)2 · 2H2O, and 1,10-phenanthroline (Phen) in 2 : 1 ratio in acetonitrile in air. Six cadmium atoms form a trigonal prismatic metal core and are connected to the carbonate anion located inside it. The structure of complex I was derived from X-ray diffraction data (CIF file CCDC no. 1912223).中文翻译:
碳酸根阴离子意外地参与六核三甲基乙酸镉(II)配合物的组装