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Catalytic activity of niobium oxide supported bimetallic nanocatalysts (IrxPt1-x/Nb2O5) for oxidation of formaldehyde at moderate temperature
Colloid and Interface Science Communications ( IF 4.5 ) Pub Date : 2020-08-07 , DOI: 10.1016/j.colcom.2020.100305
Saad H. Ammar , Mohammed D. Salman , Ruaa Fadhil Shafi

Niobium oxide (Nb2O5) nanoparticles supported bimetallic nanocatalysts (IrxPt1-x/Nb2O5) for low temperature formaldehyde oxidation were obtained. The as-synthesized IrxPt1-x/Nb2O5 nanocatalysts exhibited higher activities and stability than bare Nb2O5 for catalytic formaldehyde oxidation. The Ir:Pt ratio have considerable effects on the activity of the nanocatalyst, and the Ir0.5Pt0.5/Nb2O5 has the highest catalytic activity among all the Nb2O5 supported bimetallic nanocatalysts, and the temperature for 100% formaldehyde oxidation reached as low as 30 °C. The catalytic stability of Ir0.5Pt0.5/Nb2O5 nanocatalyst exhibited that after four reaction cycles and no catalyst deactivation was detected after 36 h operation.



中文翻译:

氧化铌负载双金属纳米催化剂(Ir x Pt 1-x / Nb 2 O 5)在中等温度下对甲醛氧化的催化活性

获得了用于低温甲醛氧化的氧化铌(Nb 2 O 5)纳米粒子负载的双金属纳米催化剂(Ir x Pt 1-x / Nb 2 O 5)。合成后的Ir x Pt 1-x / Nb 2 O 5纳米催化剂在催化甲醛氧化方面比裸Nb 2 O 5表现出更高的活性和稳定性。Ir:Pt比对纳米催化剂的活性有很大影响,Ir 0.5 Pt 0.5 / Nb 2 O 5在所有Nb 2 O 5负载的双金属纳米催化剂中具有最高的催化活性,甲醛100%氧化的温度低至30°C。Ir 0.5 Pt 0.5 / Nb 2 O 5纳米催化剂的催化稳定性表现为四个反应循环后,在运行36 h后未发现催化剂失活。

更新日期:2020-08-07
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