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Nitrogen-rich porous carbon configurate ultra-stable tin oxide anode
Colloids and Surfaces A: Physicochemical and Engineering Aspects ( IF 5.2 ) Pub Date : 2021-01-01 , DOI: 10.1016/j.colsurfa.2020.125388
Jingyi Zou , Xiaogang Sun , Rui Li , Qiang He

Abstract Glycine is pretreated and then carbonized to obtain a nitrogen-rich porous carbon materials (N-HPC materials). The N-HPC materials, with rich porous structure, can efficiently host tin oxide. The abundant nitrogen content (18.32 at%) in the N-HPC materials can shorten the diffusion distance of lithium, provide a large number of lithium ion storage sites, and enhance the conductivity. More importantly, the N-HPC materials, with high specific surface area (752 m2/g), can load tin oxide up to 1.83 mg/cm2. Further electrochemical testing, the SnO2/N-HPC battery has shown high specific capacity (1774.45 mA h·g-1 of 100 mA·g-1), excellent cycle performance (1492.92 mA h·g-1 after 100 cycles), excellent coulombic efficiency(99.78%) and low internal resistance.

中文翻译:

富氮多孔碳配置超稳定氧化锡阳极

摘要 甘氨酸经预处理后碳化得到富氮多孔碳材料(N-HPC材料)。N-HPC 材料具有丰富的多孔结构,可以有效地承载氧化锡。N-HPC材料中丰富的氮含量(18.32at%)可以缩短锂的扩散距离,提供大量的锂离子存储位点,增强导电性。更重要的是,具有高比表面积 (752 m2/g) 的 N-HPC 材料可以负载高达 1.83 mg/cm2 的氧化锡。进一步电化学测试,SnO2/N-HPC电池表现出高比容量(1774.45 mA h·g-1 of 100 mA·g-1),优异的循环性能(100次循环后1492.92 mA h·g-1),优异的库仑效率(99.78%)和低内阻。
更新日期:2021-01-01
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