Carbon Letters ( IF 4.5 ) Pub Date : 2020-08-04 , DOI: 10.1007/s42823-020-00175-5 Yun Ji Oh , Min Chang Shin , Jae Ho Kim , Seung Jae Yang
Nanostructured ZnO materials have been studied extensively because of their functional properties. This paper presents a composite material of zinc oxide quantum dots (ZnO QDs) and porous carbon using a one-step carbonization process. The direct carbonization of a metal–organic complex generates mesostructured porous carbon with a homogeneous distribution of ZnO QDs. The structural and morphological properties are investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The resulting ZnO QDs@porous carbon composite delivers a high specific capacity of 990 mAh g−1 at 100 mA g−1, 357 mAh g−1 at 2 A g−1, and high reversibility when evaluated as an anode for lithium ion batteries.
中文翻译:
通过金属-有机配合物直接碳化,可轻松制备用于高性能锂离子电池的ZnO量子点@多孔碳复合材料
纳米结构的ZnO材料由于其功能特性而被广泛研究。本文提出了一种采用一步碳化法的氧化锌量子点(ZnO QDs)和多孔碳的复合材料。金属-有机络合物的直接碳化会生成介孔结构的多孔碳,并具有均匀分布的ZnO QDs。通过X射线衍射(XRD),扫描电子显微镜(SEM)和透射电子显微镜(TEM)研究了结构和形态特性。所得的ZnO QDs @多孔碳复合材料在100 mA g -1下提供990 mAh g -1的高比容量,在2 A g -1下提供357 mAh g -1的高比容量评估为锂离子电池的负极时,具有很高的可逆性。