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Polymerization in MOF-Confined Nanospaces: Tailored Architectures, Functions, and Applications.
Langmuir ( IF 3.9 ) Pub Date : 2020-08-03 , DOI: 10.1021/acs.langmuir.0c01832
Salma Begum 1 , Zahid Hassan 2, 3 , Stefan Bräse 2, 3, 4 , Manuel Tsotsalas 1, 3
Affiliation  

This feature article describes recent trends and advances in structuring network polymers using a coordination-driven metal–organic framework (MOF)-based template approach to demonstrate the concept of crystal-controlled polymerization in confined nanospaces, forming tailored architectures ranging from simple linear one-dimensional macromolecules to tunable three-dimensional cross-linked network polymers and interwoven molecular architectures. MOF-templated network polymers combine the characteristics and advantages of crystalline MOFs (high porosity, structural regularity, and designability) with the intrinsic behaviors of soft polymers (flexibility, processability, stability, or biocompatibility) with widespread application possibilities and tunable properties. The article ends with a summary of the remaining challenges to be addressed, and future research opportunities in this field are discussed.

中文翻译:

MOF限制的纳米空间中的聚合:量身定制的体系结构,功能和应用。

这篇专题文章介绍了使用基于配位驱动的金属有机框架(MOF)的模板方法来结构化网络聚合物的最新趋势和进展,以展示受限纳米空间中晶体控制聚合的概念,形成了量身定制的体系结构,范围从简单的线性单分子-尺寸大分子,以可调的三维交联网络聚合物和交织的分子体系结构。以MOF为模板的网络聚合物将结晶MOF的特性和优势(高孔隙率,结构规则性和可设计性)与软聚合物的固有行为(柔韧性,可加工性,稳定性或生物相容性)结合起来,具有广泛的应用可能性和可调性。本文最后总结了尚待解决的挑战,
更新日期:2020-09-15
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