We conducted a simultaneous measurement of the potential of Cu²⁺, oxidation‐reduction potential (ORP), and the chemiluminescence intensity in the luminol‐H₂O₂‐KSCN‐CuSO₄‐NaOH system. Two types of chemiluminescence were identified: a very faint continuous chemiluminescence and a strong oscillating chemiluminescence. The correlation between the potential of Cu²⁺ and ORP was measured experimentally for the first time. The effect of the initial concentrations of Cu²⁺ and H₂O₂ on the overall chemiluminescence intensity and the oscillation frequency was investigated in detail. Time‐dependent concentration variation of the chemical species existing in the reaction system was calculated using a Runge‐Kutta method. Two elementary chemical reactions not considered previously were taken into consideration. The overall experimental behavior was well explainable with our simulation. Based upon the comparison of our simulation with the experiment, we proposed that the strong oscillating chemiluminescence was induced by the reaction of luminol with ·OS(O)CN.

中文翻译：

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鲁米诺-H2O2-KSCN-CuSO4-NaOH体系中的化学发光振荡反应机理

我们同时测量了Luminol‐H ₂ O ₂ ‐KSCN‐CuSO ₄ ‐ NaOH系统中Cu ²⁺的电位，氧化还原电位（ORP）和化学发光强度。鉴定出两种类型的化学发光：非常微弱的连续化学发光和强烈的振荡化学发光。首次通过实验测量了Cu ²⁺和ORP电位之间的相关性。Cu ²⁺和H ₂ O ₂初始浓度的影响对整体化学发光强度和振荡频率进行了详细研究。使用Runge-Kutta方法计算反应系统中存在的化学物质随时间的浓度变化。考虑了先前未考虑的两个基本化学反应。我们的仿真可以很好地解释整体实验行为。在将仿真结果与实验结果进行比较的基础上，我们提出了鲁米诺与·OS（O）CN的反应诱导了强烈的振荡化学发光。