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Design of a new electrochemical sensor based on the CuO/GO nanocomposites: simultaneous determination of Sudan I and bisphenol A
Journal of the Iranian Chemical Society ( IF 2.4 ) Pub Date : 2020-08-04 , DOI: 10.1007/s13738-020-02016-8
Fatemeh Ebrahimi-Tazangi , Hadi Beitollahi , Hoda Hekmatara , Jamileh Seyed-Yazdi

The present research reported the synthesis and electrochemical activities of CuO/GO nanocomposites modified screen-printed graphite electrode (CuO/GO/SPGE) as one of the highly sensitive electrochemical sensors to determine Sudan I. Therefore, we utilized cyclic voltammetry, chronoamperometry, and differential pulse voltammetry (DPV) to examine electrochemical behavior of Sudan I at CuO/GO/SPGE. This modified electrode shows very good electrochemical activities to oxidize Sudan I with a potential shift about 220 mV toward a less positive potential. In optimum conditions, linear calibration ranged between 0.3 and 700.0 µM and limit of detection equal to 0.093 µM is obtained to measure Sudan I concentration using the DPV method. In addition, the modified electrode could be applied to determine simultaneously Sudan I and bisphenol A at potentials of 370 and 510, respectively. It was proved that the proposed CuO/GO/SPGE can be performed to detect Sudan I and bisphenol A into the food as well as water samples, and reasonable results were obtained.



中文翻译:

基于CuO / GO纳米复合材料的新型电化学传感器的设计:同时测定苏丹I和双酚A

本研究报道了CuO / GO纳米复合材料修饰的丝网印刷石墨电极(CuO / GO / SPGE)的合成和电化学活性,作为测定苏丹红I的高灵敏度电化学传感器之一。因此,我们利用循环伏安法,计时电流法和差动脉冲伏安法(DPV)来研究苏丹I在CuO / GO / SPGE上的电化学行为。这种修饰的电极表现出非常好的电化学活性,可以氧化苏丹I,电位约为220 mV,朝较低的正电位移动。在最佳条件下,使用DPV方法测量苏丹I浓度时,线性校准的范围在0.3到700.0 µM之间,检出限等于0.093 µM。此外,改进的电极可用于同时测定苏丹Ⅰ和双酚A的电位,分别为370和510。实践证明,所提出的CuO / GO / SPGE方法可用于食品和水样中苏丹红I和双酚A的检测,并获得合理的结果。

更新日期:2020-08-04
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