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Modelling and optimization of methanol synthesis from hydrogen and CO2
Journal of Environmental Chemical Engineering ( IF 7.7 ) Pub Date : 2020-08-02 , DOI: 10.1016/j.jece.2020.104314
Ahmad Rafiee

In this paper, CO2 hydrogenation to methanol is investigated with three objective functions, i.e. maximization of reactor productivity, CO2 utilization, and hydrogen conversion. Key performance indicators of methanol production via conventional and CO2 hydrogenation routes are compared.

The results suggest that the methanol production rate with an inlet H2/CO2 of 3 is ca. 59 % greater than the case with the inlet H2/CO2 composition of 2. The overall hydrogen and CO2 conversion of the cases with the inlet H2/CO2 of 3 is greater than the reactor system with the inlet H2/CO2 of 2.

For each objective function criteria, the analysis shows that increasing the H2/CO2 to the methanol reactor increases the natural gas consumption in the conventional route and the higher the inlet H2/CO2 ratio, the higher the CO2 emission is. If the inlet hydrogen is produced via water electrolysis, the CO2 emission of the CO2 hydrogenation process route will be negative.



中文翻译:

氢气和CO 2合成甲醇的建模和优化

本文以三个目标函数为研究对象,研究了CO 2加氢制甲醇的最大功能,即反应器生产率的最大化,CO 2利用率和氢转化率。比较了通过常规和CO 2加氢路线生产甲醇的关键性能指标。

结果表明,入口H 2 / CO 2为3时,甲醇的产率约为。59%大于与入口小时壳体2 / CO 2的2.总体氢组合物和CO 2转化率的与入口小时箱子2 / CO 2的3比与入口小时反应器系统提供更大的2 / CO 2之2。

对于每个目标函数标准,分析表明,增加甲醇反应器中的H 2 / CO 2会增加常规路线中的天然气消耗,并且进口H 2 / CO 2比率越高,CO 2排放就越高。如果入口氢是通过水电解产生的,则CO 2加氢工艺路线的CO 2排放将为负。

更新日期:2020-08-03
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